产品名称

英文名称：1-(Trimethylsilyl)imidazole

同义词

18156-74-6、N-(Trimethylsilyl)imidazole、1-(Trimethylsilyl)imidazole、1-(Trimethylsilyl)-1H-imidazole、N-Trimethylsilylimidazole、1H-Imidazole, 1-(trimethylsilyl)-、TSIM、1-trimethylsilylimidazole、imidazol-1-yl(trimethyl)silane、(Trimethylsilyl)imidazole、Imidazol、1-(三甲基硅基)咪唑、N-三甲基硅基咪唑、三甲基甲硅烷基咪唑、N-三甲基硅烷基咪唑

产品性质

CAS编号：18156-74-6

分子式：C6H12N2Si

分子量：140.26

Beilstein号：606148

EC号：242-040-3

MDL号：MFCD00005280

PubChem编号：28925

别名：1-(三甲基硅基)咪唑|N-三甲基硅基咪唑|三甲基甲硅烷基咪唑|N-三甲基硅烷基咪唑

英文别名：18156-74-6|N-(Trimethylsilyl)imidazole|1-(Trimethylsilyl)imidazole|1-(Trimethylsilyl)-1H-imidazole|N-Trimethylsilylimidazole|1H-Imidazole, 1-(trimethylsilyl)-|TSIM|1-trimethylsilylimidazole|imidazol-1-yl(trimethyl)silane|(Trimethylsilyl)imidazole|Imidazol

规格或纯度：97%

英文名称：1-(Trimethylsilyl)imidazole

应用：1-（三甲基硅烷基）咪唑可作为 N 、 O -双（三甲基硅烷基）三氟乙酰胺 (BSTFA) 和 N -甲基- N -（三甲基硅烷基）三氟乙酰胺 (MSTFA) 的有效替代品，用于钛取代介孔分子筛 Ti-MCM-41 的有效硅烷化。该工艺提高了 Ti-MCM-41 催化剂的疏水性和催化活性。

储存温度：2-8°C储存,避光,充氩

运输条件：冰袋运输

产品介绍：水中分解。 1-（三甲基硅烷基）咪唑可作为 N 、 O -双（三甲基硅烷基）三氟乙酰胺 (BSTFA) 和 N -甲基- N -（三甲基硅烷基）三氟乙酰胺 (MSTFA) 的有效替代品，用于钛取代介孔分子筛 Ti-MCM-41 的有效硅烷化。该工艺提高了 Ti-MCM-41 催化剂的疏水性和催化活性。1-(Trimethylsilyl)imidazole (TMSI) was used for derivatization of carbohydrates into trimethylsilyl ethers. It was also used to synthesize polysubstituted chiral spirotetrahydropyrans and as silylating reagent for the protection of hydroxyl groups in the presence of amine functionalities.

IUPAC Name：imidazol-1-yl(trimethyl)silane

INCHI：InChI=1S/C6H12N2Si/c1-9(2,3)8-5-4-7-6-8/h4-6H,1-3H3

InChi Key：YKFRUJSEPGHZFJ-UHFFFAOYSA-N

Canonical SMILES：C[Si](C)(C)N1C=CN=C1

Isomeric SMILES：C[Si](C)(C)N1C=CN=C1

WGK Germany：3

RTECS：NI8700000

PubChem CID：28925

Reaxy-Rn：606148

溶解性：Miscible with most common organic solvents. It decomposes in water.

密度：0.957

敏感性：对光线、湿度、热 敏感

折光率：n20/D 1.475

闪点(℉)：42.8 °F

闪点(℃)：6 °C

沸点：93-94°C/14mmHg

熔点：-42°C

象形图：

信号词：Danger

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH411 Toxic to aquatic life with long lasting effectsH314 Causes severe skin burns and eye damageH302 Harmful if swallowedH318 Causes serious eye damageH225 Highly Flammable liquid and vaporH400 Very toxic to aquatic lifeH226 Flammable liquid and vaporH410 Very toxic to aquatic life with long lasting effectsH360 May damage fertility or the unborn childH360D May damage the unborn child

预防措施声明：P261,P305+P351+P338,P273,P280,P370+P378,P210,P302+P352,P321,P405,P501,P233,P240,P264,P403+P235,P260,P303+P361+P353,P271,P241,P270,P301+P330+P331,P304+P340,P363,P403+P233,P362+P364,P391,P330,P242,P243,P203,P264+P265,P301+P317,P305+P354+P338,P318,P317,P337+

个人防护装备：Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

产品包装