产品名称

英文名称：Bicyclo[2.2.1]hepta-2,5-diene-rhodium chloride dimer

同义词

12257-42-0、bicyclo[2.2.1]hepta-2,5-diene;rhodium(2+);dichloride、EINECS 235-510-4、DTXSID10924203、(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER、FT-0696287、Rhodium(2+) chloride--bicyclo[2.2.1]hepta-2,5-diene (1/2/2)、Bis((2,3,5,6-eta)-bicyclo(2.2.1)he、Chiralyst P461、降冰片二烯氯化铑二聚体、二氯化二铑(双降冰片二烯)、氯化降冰片二烯铑二聚物、二氯双(降冰片二烯)二铑、二氯化二铑(双降冰片二烯) 铑

产品性质

CAS编号：12257-42-0

分子式：C14H16Cl2Rh2

分子量：460.99

EC号：235-510-4

MDL号：MFCD00198060

PubChem编号：114600

别名：Chiralyst P461|降冰片二烯氯化铑二聚体|二氯化二铑(双降冰片二烯)|氯化降冰片二烯铑二聚物|二氯双(降冰片二烯)二铑|二氯化二铑(双降冰片二烯) 铑

英文别名：12257-42-0|bicyclo[2.2.1]hepta-2,5-diene;rhodium(2+);dichloride|EINECS 235-510-4|DTXSID10924203|(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER|FT-0696287|Rhodium(2+) chloride--bicyclo[2.2.1]hepta-2,5-diene (1/2/2)|Bis((2,3,5,6-eta)-bicyclo(2.2.1)he

规格或纯度：96%

英文名称：Bicyclo[2.2.1]hepta-2,5-diene-rhodium chloride dimer

储存温度：室温,充氩

运输条件：常规运输

产品介绍：不对称催化交叉偶联反应催化剂,硅氢化催化剂Precatalysts for Asymmetric and Cross-Coupling Catalysis，Hydrosilylation CatalystsCatalyst for valence isomerization and N-heterocyclization; incombination with phosphorus ligands are catalysts for hydrogenationof many functional groups and hydroformylation; withchiral ligands are catalysts for asymmetric hydrogenation.Product classM-C, Homogeneous Catalysts, Diene/Dienyl LigandsReaction typeHydrogenation, Asymmetric Reactions, CH-Activation, Hydroformylation, Asymmetric Hydrogenation, Hydrosilylation, IsomerizationChemical propertiesChemical formulaC14H16Cl2Rh2Empirical formula[Rh(nbd)Cl]2Molecular weight461.00MetalRhTheoretical metal content45Physical statecrystallineColororange

IUPAC Name：bicyclo[2.2.1]hepta-2,5-diene;rhodium(2+);dichloride

INCHI：InChI=1S/2C7H8.2ClH.Rh/c2*1-2-7-4-3-6(1)5-7;;;/h2*1-4,6-7H,5H2;2*1H;/q;;;;+2/p-2

InChi Key：HCZNBZKRJTYNCE-UHFFFAOYSA-L

Canonical SMILES：C1C2C=CC1C=C2.C1C2C=CC1C=C2.[Cl-].[Cl-].[Rh+2]

Isomeric SMILES：C1C2C=CC1C=C2.C1C2C=CC1C=C2.[Cl-].[Cl-].[Rh+2]

WGK Germany：3

PubChem CID：114600

Reaxy-Rn：16998692

溶解性：Slightly soluble in acetone, chloroform, methanol and insoluble in water.

敏感性：对空气敏感；对湿度敏感

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH413 May cause long lasting harmful effects to aquatic lifeH302 Harmful if swallowedH312 Harmful in contact with skinH332 Harmful if inhaled

预防措施声明：P261,P305+P351+P338,P273,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P330,P264+P265,P301+P317,P317,P337+P317,P332+P317,P319

个人防护装备：Eyeshields, Gloves, type N95 (US)

产品包装