产品名称

英文名称：Bis(tri-tert-butylphosphine)palladium(0)

同义词

53199-31-8、Bis(tri-tert-butylphosphine)palladium(0)、BIS(TRI-TERT-BUTYLPHOSPHINE)PALLADIUM、Bis(tri-t-butylphosphine)palladium(0)、palladium;tritert-butylphosphane、bis(tri-tert-butylphosphane) palladium、pd(p(tbu)3)2、BIS(TRI-T-BUTYLPHOSPHINE)PALLADIUM、Palladi、Fu catalyst、二(三叔丁基膦)钯(0)、Pd(t-Bu3P)2

产品性质

CAS编号：53199-31-8

分子式：C24H54P2Pd

分子量：511.05

MDL号：MFCD03094580

PubChem编号：2734558

别名：Fu catalyst|二(三叔丁基膦)钯(0)|Pd(t-Bu3P)2

英文别名：53199-31-8|Bis(tri-tert-butylphosphine)palladium(0)|BIS(TRI-TERT-BUTYLPHOSPHINE)PALLADIUM|Bis(tri-t-butylphosphine)palladium(0)|palladium;tritert-butylphosphane|bis(tri-tert-butylphosphane) palladium|pd(p(tbu)3)2|BIS(TRI-T-BUTYLPHOSPHINE)PALLADIUM|Palladi

规格或纯度：Pd 20.8%

英文名称：Bis(tri-tert-butylphosphine)palladium(0)

储存温度：-20°C储存,充氩

运输条件：超低温冰袋运输

产品介绍：不溶水。 溶于甲苯、苯，微溶于丙酮、氯仿。 芳基与氯乙烯的交叉耦合。Product classM-P, Homogeneous Catalysts, M-C, Alkyl Ligands, Monodentate LigandsReaction typeCross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Carbonylation, Mizoroki Heck Coupling Reaction, Negishi Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling ReactionChemical propertiesChemical formulaC24H54P2PdEmpirical formula[Pd(P(tBu3))2]Molecular weight511.06MetalPdTheoretical metal content21Physical statecrystallineColorwhiteApplications & referencesDiastereoselctive synthesis of isochromans using a Palladium catalyzed carboiodination.Reference Org. Lett. 2012, 14, 4806. (DOI 10.1021/ol302111y)High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl halides.Reference J. Org. Chem. 2010, 75, 6998. (DOI 10.1021/jo101433g)Arylation of hydrosiloxanes for the synthesis of symmetrical and unsymmetrical siloxanes. They are interesting substrates for the usage as liquid crystals, starting materials for cross coupling reactions and biologically active compounds.Reference Chem. Comm. 2013, 49, 11275. (DOI 10.1039/c3cc46294c)

IUPAC Name：palladium;tritert-butylphosphane

INCHI：InChI=1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;

InChi Key：MXQOYLRVSVOCQT-UHFFFAOYSA-N

Canonical SMILES：CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C.[Pd]

Isomeric SMILES：CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C.[Pd]

WGK Germany：3

PubChem CID：2734558

Reaxy-Rn：14300595

溶解性：Soluble in toluene benzene, slight soluble in chloroform and acetone. Decomposes in water.

敏感性：对空气、热、光和湿度敏感

熔点：>300°C

象形图：

信号词：Danger

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH413 May cause long lasting harmful effects to aquatic lifeH302 Harmful if swallowedH228 Flammable solidH312 Harmful in contact with skinH332 Harmful if inhaled

预防措施声明：P261,P305+P351+P338,P273,P280,P370+P378,P210,P302+P352,P321,P405,P501,P240,P264,P271,P241,P270,P304+P340,P403+P233,P362+P364,P330,P264+P265,P301+P317,P317,P337+P317,P332+P317,P319

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