2-二环己基磷-2',6'-二异丙氧基-1,1'-联苯

中文名称： 2-二环己基磷-2',6'-二异丙氧基-1,1'-联苯

英文名称： RuPhos

CAS： 787618-22-8

分子式： C₃₀H₄₃O₂P

分子量： 467

EINECS号： 616-653-5

中文同义词 2-二环己基磷-2',6'-二异丙氧基-1,1'-联苯英文同义词

RuPhos

基本性质

溶解度	Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
形态	Powder
颜色	white
敏感性	对空气敏感
PubChem编号	16217985
规格或纯度	98%
运输条件	常规运输
IUPAC Name	dicyclohexyl-[2-[2,6-di(propan-2-yloxy)phenyl]phenyl]phosphane

安全信息

危险品标志	Xn
安全说明	26-36/37/39
WGK Germany	3
TSCA	No
海关编码	29310099

CHS信息

生产方法及用途

用途	大位阻膦配体，可用于氨基乙基三氟硼酸酯与缺电子芳基溴的钯催化交叉偶联反应。
产品介绍	大位阻膦配体，可用于氨基乙基三氟硼酸酯与缺电子芳基溴的钯催化交叉偶联反应ligand for Arylations Buchwald-Hartwig Cross Coupling Reaction Negishi Coupling Sonogashira Coupling Suzuki-Miyaura CouplingBulky phosphine ligand used in a palladium-catalyzed cross-coupling of aminoethyltrifluoroborates with electron-poor aryl bromides.ApplicationFinds application in Buchwald-Hartwig cross coupling reactions, Arylation, Negishi and Sonogashira coupling reactions. A Ruphos-mediated Suzuki cross-coupling between (hetero)aryl bromides and secondary alkyltrifluoroborates is described using palladium catalysis. The Ruphos ligand showed superior properties as compared to S-Phos in this type of reaction. This method constitutes a valuable extension to current methods for the straightforward production of secondary-alkylated (hetero)aryl derivatives.

用途

大位阻膦配体，可用于氨基乙基三氟硼酸酯与缺电子芳基溴的钯催化交叉偶联反应。

产品介绍

大位阻膦配体，可用于氨基乙基三氟硼酸酯与缺电子芳基溴的钯催化交叉偶联反应ligand for Arylations Buchwald-Hartwig Cross Coupling Reaction Negishi Coupling Sonogashira Coupling Suzuki-Miyaura CouplingBulky phosphine ligand used in a palladium-catalyzed cross-coupling of aminoethyltrifluoroborates with electron-poor aryl bromides.ApplicationFinds application in Buchwald-Hartwig cross coupling reactions, Arylation, Negishi and Sonogashira coupling reactions. A Ruphos-mediated Suzuki cross-coupling between (hetero)aryl bromides and secondary alkyltrifluoroborates is described using palladium catalysis. The Ruphos ligand showed superior properties as compared to S-Phos in this type of reaction. This method constitutes a valuable extension to current methods for the straightforward production of secondary-alkylated (hetero)aryl derivatives.